Microstructure of Cement Paste with Expansive Additives under Free and Restrained Conditions

Abstract

Expansive additives (EAs) have been widely used to reduce the risk of cracking due to shrinkage. Such additives cause early age expansion of concrete due to the formation of Portlandite and Ettringite in the pores of the cement paste, which affects the cement paste's microstructure. The presence of external restraints in the form of reinforcement and support affects the expansion and, ultimately the microstructure of cement paste. In the current study, the microstructure of cement paste with expansive additives is studied using mercury intrusion porosimetry (MIP). A free lime-based EA, with 10 and 15% (by weight) cement replacement ratios, is studied in the current study. The porosity and pore size distribution of the cement paste with EA were studied under free and restrained conditions. Results show that the under the stress-free condition, the porosity of the paste increased, while under the restrained condition, the porosity remained much similar to the reference case of OPC. Further, the pore size distribution of the cement paste with EA under free and restrained conditions is explained, and the effect of EA and restraint on the microstructure is discussed.

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